For a perfect semiconductor or insulator system, the value of band gap and the location of band gap with respect to the Fermi level do not change with respect to the size of unit cell.
Since the curvatures of valence band minimum of conduction band maximum correspond to the effective mass of electron or hole, they do not vary with the use of different size of unit cell.
Since the number of atoms in the unit cell depends on the size of unit cell, the number of valence bands below the Fermi level will vary with the size of unit cell. However, the number of conduction bands above the Fermi level is not a physical quantity of interest.